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Physical chemistry (MSM-ME3)15 ECTS (englische Bezeichnung: Physical chemistry)
Modulverantwortliche/r: Rainer Fink Lehrende:
Thomas Drewello, Franziska Gröhn, Dirk Guldi, Jörg Libuda, Guido Sauer, Assistenten, Rainer Fink
Start semester: |
WS 2015/2016 | Duration: |
2 semester | Cycle: |
halbjährlich (WS+SS) |
Präsenzzeit: |
210 Std. | Eigenstudium: |
240 Std. | Language: |
Englisch |
Lectures:
Please check UnivIS for further lectures/seminars
NB: no overlap with courses in Mandatory Module allowed!
- Mandatory courses:
- A. Lab course:
(7/8 experiments from advanced PC lab; 4 experiments may be replaced by a project course in one of the PC work groups – with prior approval of the lab coordinator (7LAB))
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Lab Course Physical Chemistry (WS 2015/2016)
(Praktikum, 7 SWS, Guido Sauer et al., Zeit n.V., P 0.72; Zeit nach Vereinbarung: Mo-Fr ganztägig (ab 16.11.2015); Anmeldung Mo-Fr 8:00-12:00 (ab 16.11.2015))
- B. Lectures & Seminars:
(please choose additional 6L and 2S), e.g.
- B1: Characterization of Nanosized Systems (2L)
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Characterization of Nanosized Systems (WS 2015/2016)
(Vorlesung, 2 SWS, Dirk Guldi, block seminar 6.10.2015-9.10.2015 Tue, Wed, Thu, Fri, 9:00 - 12:00, 14:00 - 15:30, P 3.88; in WS 15/16 block course; in WS 16/17 the lecture will be held in the usual lecture period)
- B2: Organic thin films (2L/1S)
- B3: Modern Methods in Mass Spectrometry (2L/1S)
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Modern Methods in Mass Spectrometry (WS 2015/2016)
(Vorlesung, 2 SWS, Thomas Drewello, Wed, 8:15 - 10:00, P 3.88)
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Seminar Modern Methods in Mass Spectrometry (WS 2015/2016)
(Seminar, 1 SWS, Thomas Drewello et al., Wed, 10:00 - 10:45, P 3.88)
- B4: Symmetry and Group Theory (2L/1S)
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Symmetry and Group Theory (WS 2015/2016)
(Vorlesung, 2 SWS, Jörg Libuda, Tue, 8:15 - 10:00, P 3.70)
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Seminar Symmetry and Group Theory (WS 2015/2016)
(Seminar, 1 SWS, Jörg Libuda et al., Tue, 10:00 - 10:45, P 3.70)
- B5: Interface Science and Catalysis (2L/1S)
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Advanced Physical Chemistry I - Interface Science and Catalysis (WS 2015/2016)
(Vorlesung, 2 SWS, Jörg Libuda, Thu, 13:15 - 15:00, H3 Egerlandstr.3)
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Advanced Physical Chemistry I - Seminar Interface Science and Catalysis (WS 2015/2016)
(Seminar, 1 SWS, Jörg Libuda, Thu, 15:00 - 15:45, H3 Egerlandstr.3)
- B6: Solar Energy conversion (2L)
- B7: Formation and characterization of supramolecular nanoparticles (2L/1S)
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Formation and Characterization of Supramolecular Nanoparticles (WS 2015/2016)
(Vorlesung, 2 SWS, Franziska Gröhn, Mon, 14:15 - 16:00, H3 Egerlandstr.3; starting 19.10.2015)
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Seminar Formation and Characterization of Supramolecular Nanoparticles (WS 2015/2016)
(Seminar, 1 SWS, Franziska Gröhn et al., Thu, 12:15 - 13:00, P 3.88; starting 22.10.2015)
Empfohlene Voraussetzungen:
Admission to the M. Sc. program Molecular Science or Chemistry
Inhalt:
A: Advanced course lab experiments and/or lab project close to actual research topics
B1: Fullerenes; carbon nanotubes; graphene; endohedral metallo fullerenes; peapods; carbon nanohorns and nanoonions; synthesis and analytical techniques.
B2: Preparation techniques (Langmuir-Blodgett films, self-assembled
monolayers, sublimation, spin-casting, spraying), self-assembly, structural and spectroscopic analytical techniques, heterostructures, phase diagrams.
B3: Ionisation methods (EI, CI, FD, FI, SIMS, FAB, MALDI and ESI),
ion formation mechanisms, analysers (ToF, sector field, quadrupole, ion trap, FT-ICR, orbitrap), tandem mass spectrometry, ion activation
and fragmentation, thermochemical and analytical applications.
B4: Symmetry of molecules, symmetry operations and point groups; symmetry of periodic systems; compact course to group theory; group theory and quantum mechanics; symmetry and spectroscopy: vibrational spectroscopies; tensor description of physical properties; band structures.
B5: Surfaces of metals, oxides and ionic crystals; surface analytical techniques; bonding of molecules to surfaces: bonding mechanisms; Blyholder model; adsorbate interactions and superstructures; temperature programmed desorption/reaction; concepts
and definitions in catalysis; microkinetics of catalystic processes; transport limitations; surface dynamics and surface kinetics; model
catalysis.
B6:
Energy portfolio; electron transfer; Si solar cells; dye-sensitized
solar cells; organic photovoltaics; multiple excition generation cells; photosynthesis; artificial photosynthesis
B7:
Self-assembly of surfactants; self-assembly of more complex amphiphilic molecules; nteraction forces in colloidal systems; osmometry; light scattering; form factor as key to particle shape; dynamic Light Scattering; fractionating Methods for Nanoparticle Analytics; combined Use of Characterization Methods; supramolecular nanoparticles by H-bridges and metal coordination; special Behaviour of polyelectrolytes; nanostructures with polyelectrolytes
Lernziele und Kompetenzen:
The students are able
to understand the advanced principles of experimental techniques in physical chemistry
to evaluate the application of experimental and/or theoretical techniques in modern material science/materials research
to plan and perform advanced lab experiments and/or lab project related to actual research topics in physical chemistry
to utilize selected preparation techniques for sample preparation
to apply and understand modern experimental methods for sample characterization
to interpret and to critically summarize their experimental results in written form (lab report, sometimes in paper-style format).
Literatur:
Manuscripts for most lectures available online (check StudOn or lecturers’ website)
Bemerkung:
Courses of study for which the module is acceptable: M.Sc. Molecular Science (as mandatory elective module) and
M. Sc. Chemistry (as elective module). *)
*) No overlap with courses in Mandatory elective Module “Interface phenomena” or Mandatory Module allowed!
Organisatorisches:
Intended stage in the degree course: Mandatory elective module (Wahlpflichtmodul) or Elective Module (Wahlmodul) semester 1 - 3
Frequency of offer:
A: upon appointment with course lab supervisor or research lab supervisors
B1-B5, B7: winter term, B6: summer term
Studien-/Prüfungsleistungen:
Physikalische Chemie - Physical Chemistry (Prüfungsnummer: 30803)
(englischer Titel: Physical Chemistry)
- Prüfungsleistung, mündliche Prüfung, Dauer (in Minuten): 45, benotet
- Anteil an der Berechnung der Modulnote: 100.0 %
- weitere Erläuterungen:
Assessment and examinations:
Portfolio: Depending on the choice of the module
LAB (SL, AP)
Lab course protocol(s) without marks
+ oral examination (45 min, 2 examiners)
Calculation of the grade for the module: 100% from oral examination
- Prüfungssprache: Englisch
- Erstablegung: SS 2016
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